Total Synthesis and Conformational Study of Callyaerin A: Anti‐Tubercular Cyclic Peptide Bearing a Rare Rigidifying (Z)‐2,3‐ Diaminoacrylamide Moiety
S Zhang, LM De Leon Rodriguez… - Angewandte …, 2018 - Wiley Online Library
The first synthesis of the anti‐TB cyclic peptide callyaerin A (1), containing a rare (Z)‐2, 3‐
diaminoacrylamide bridging motif, is reported. Fmoc‐formylglycine‐diethylacetal was used
as a masked equivalent of formylglycine in the synthesis of the linear precursor to 1 …
diaminoacrylamide bridging motif, is reported. Fmoc‐formylglycine‐diethylacetal was used
as a masked equivalent of formylglycine in the synthesis of the linear precursor to 1 …
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