Development of aspartic acid ligation for peptide cyclization derived from serine/threonine ligation
Based on a mechanism analogous to the serine/threonine ligation, the aspartic acid ligation,
which is facilitated by the γ-amino alcohol based ligation and oxidation, is developed and
applied to the synthesis of cyclic peptides. The γ-hydroxyl group triggers the ring-chain …
which is facilitated by the γ-amino alcohol based ligation and oxidation, is developed and
applied to the synthesis of cyclic peptides. The γ-hydroxyl group triggers the ring-chain …
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