2018年12月20日星期四

Photoredox/Brønsted acid co-catalysis enabling decarboxylative coupling of amino acid and peptide redox-active esters with N-heteroarenes

Photoredox/Brønsted acid co-catalysis enabling decarboxylative coupling of amino acid and peptide redox-active esters with N-heteroarenes

WM Cheng, R Shang, Y Fu - ACS Catalysis, 2016 - ACS Publications
An iridium photoredox catalyst in combination with a phosphoric acid catalyzes the
decarboxylative α-aminoalkylation of natural and unnatural α-amino acid-derived redox-
active esters (N-hydroxyphthalimide esters) with a broad substrate scope of N-heteroarenes …


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