Examination of mercaptobenzyl sulfonates as catalysts for native chemical ligation: application to the assembly of a glycosylated Glucagon-Like Peptide 1 (GLP-1) …

Examination of mercaptobenzyl sulfonates as catalysts for native chemical ligation: application to the assembly of a glycosylated Glucagon-Like Peptide 1 (GLP-1) …

T MeiáSze, AF áBongat White - Chemical Communications, 2015 - pubs.rsc.org

3/4-Mercaptobenzyl sulfonates were investigated as aryl thiol catalysts for native chemical
ligation (NCL). Whilst catalysing NCL processes at a similar rate to 4-mercaptophenyl acetic
acid (MPAA), the increased polarity and solubility of 3-mercaptobenzyl sulfonate in particular …

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